@inbook{73b81e645e53459a81578cd082abb325,
title = "Transition metal complexes of borane and borohydride ligand architectures containing a single tethering supporting unit",
abstract = "This chapter provides a highlight on some of the recent advances and structural features of neutral borane and anionic borohydride units which contain a single tethered supporting unit. The supporting units covered include one-, two- and three-atom bridges. It focuses on the synthesis and characterisation of complexes formed, looking in detail into the spectroscopic features of the interactions between the boron-based species and the metal centre. It will also look at the structural features of the bonding by referring to X-ray crystallography data available. The review explores the range of possible interactions and potential reactivity at the boron centres. It also explores some early examples with a greater focus on three-atom supporting units and analyses the potential for delivery of hydrogen from boron to the metal centre to generate metal boron bonds.",
keywords = "Boron, hydrogen, Transition metals, Coordination Chemistry, Organometallic Chemistry, Borane, borohydride, scorpionate ligands",
author = "{Da Costa}, {Rosenildo C.} and Owen, {Gareth R.}",
note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = nov,
day = "9",
doi = "10.1039/9781788017077-00144",
language = "English",
isbn = "978-1-78801-691-9",
volume = "43",
series = "Organometallic Chemistry",
publisher = "Royal Society of Chemistry",
pages = "144--185",
editor = "Patmore, {Nathan J.} and Elliott, {Paul I. P.}",
booktitle = "Organometallic Chemistry",
address = "United Kingdom",
}