Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols

Mathew W.C. Robinson; A. Matthew Davies; Ian Mabbett; Thomas E. Davies; David C. Apperley; Stuart H. Taylor; Andrew Graham

doi:10.1016/j.molcata.2010.06.018

Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols

Mathew W.C. Robinson, A. Matthew Davies, Ian Mabbett, Thomas E. Davies, David C. Apperley, Stuart H. Taylor, Andrew Graham

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

1 Downloads (Pure)

Abstract

The ability of nanoporous aluminosilicate materials, synthesized using an evaporation-induced self-assembly (EISA) approach, to function as catalysts for the formation of ß-amino alcohols from aromatic amines and epoxides was assessed. Materials containing high aluminium loadings displayed catalytic activity, giving the desired ß-amino alcohols in high yield and with high selectivity for the Markovnikov addition product. These materials exhibited nanoporous pores, typically 1.34–1.49 nm, with a narrow pore size distribution and the expected large surface areas.

Original language	English
Pages (from-to)	57 - 63
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	329
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2010.06.018
Publication status	Published - 17 Aug 2010

Keywords

nanoporous aluminosilicate
heterogeneous catalysts
synthesis
β-amino alcohols

Access to Document

10.1016/j.molcata.2010.06.018Licence: CC BY-NC-ND

1 Doctoral Thesis

Solid Lewis and Brønsted Acids and Their Application as Environmentally Benign Catalysts
Robinson, M., 2008
Research output: Types of Thesis › Doctoral Thesis

Cite this

Robinson, M. W. C., Davies, A. M., Mabbett, I., Davies, T. E., Apperley, D. C., Taylor, S. H., & Graham, A. (2010). Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols. Journal of Molecular Catalysis A: Chemical, 329(1-2), 57 - 63. https://doi.org/10.1016/j.molcata.2010.06.018

@article{18bca20b510d4e9a872a28d27a8b770d,

title = "Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols",

abstract = "The ability of nanoporous aluminosilicate materials, synthesized using an evaporation-induced self-assembly (EISA) approach, to function as catalysts for the formation of {\ss}-amino alcohols from aromatic amines and epoxides was assessed. Materials containing high aluminium loadings displayed catalytic activity, giving the desired {\ss}-amino alcohols in high yield and with high selectivity for the Markovnikov addition product. These materials exhibited nanoporous pores, typically 1.34–1.49 nm, with a narrow pore size distribution and the expected large surface areas.",

keywords = "nanoporous aluminosilicate, heterogeneous catalysts, synthesis, β-amino alcohols",

author = "Robinson, {Mathew W.C.} and Davies, {A. Matthew} and Ian Mabbett and Davies, {Thomas E.} and Apperley, {David C.} and Taylor, {Stuart H.} and Andrew Graham",

year = "2010",

month = aug,

day = "17",

doi = "10.1016/j.molcata.2010.06.018",

language = "English",

volume = "329",

pages = "57 -- 63",

journal = "Journal of Molecular Catalysis A: Chemical",

publisher = "Elsevier",

number = "1-2",

}

Robinson, MWC, Davies, AM, Mabbett, I, Davies, TE, Apperley, DC, Taylor, SH & Graham, A 2010, 'Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols', Journal of Molecular Catalysis A: Chemical, vol. 329, no. 1-2, pp. 57 - 63. https://doi.org/10.1016/j.molcata.2010.06.018

Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols. / Robinson, Mathew W.C.; Davies, A. Matthew; Mabbett, Ian et al.
In: Journal of Molecular Catalysis A: Chemical, Vol. 329, No. 1-2, 17.08.2010, p. 57 - 63.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols

AU - Robinson, Mathew W.C.

AU - Davies, A. Matthew

AU - Mabbett, Ian

AU - Davies, Thomas E.

AU - Apperley, David C.

AU - Taylor, Stuart H.

AU - Graham, Andrew

PY - 2010/8/17

Y1 - 2010/8/17

N2 - The ability of nanoporous aluminosilicate materials, synthesized using an evaporation-induced self-assembly (EISA) approach, to function as catalysts for the formation of ß-amino alcohols from aromatic amines and epoxides was assessed. Materials containing high aluminium loadings displayed catalytic activity, giving the desired ß-amino alcohols in high yield and with high selectivity for the Markovnikov addition product. These materials exhibited nanoporous pores, typically 1.34–1.49 nm, with a narrow pore size distribution and the expected large surface areas.

AB - The ability of nanoporous aluminosilicate materials, synthesized using an evaporation-induced self-assembly (EISA) approach, to function as catalysts for the formation of ß-amino alcohols from aromatic amines and epoxides was assessed. Materials containing high aluminium loadings displayed catalytic activity, giving the desired ß-amino alcohols in high yield and with high selectivity for the Markovnikov addition product. These materials exhibited nanoporous pores, typically 1.34–1.49 nm, with a narrow pore size distribution and the expected large surface areas.

KW - nanoporous aluminosilicate

KW - heterogeneous catalysts

KW - synthesis

KW - β-amino alcohols

U2 - 10.1016/j.molcata.2010.06.018

DO - 10.1016/j.molcata.2010.06.018

M3 - Article

VL - 329

SP - 57

EP - 63

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Synthesis of nanoporous aluminosilicate materials and their application as highly selective heterogeneous catalysts for the synthesis of β-amino alcohols

Abstract

Keywords

Access to Document

Fingerprint

Research output

Solid Lewis and Brønsted Acids and Their Application as Environmentally Benign Catalysts

Cite this