Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors

Miriam Slivarichova; Mairi F. Haddow; Hafiizah Othman; Gareth Owen

doi:10.1002/ejic.201300106

Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors

Miriam Slivarichova, Mairi F. Haddow, Hafiizah Othman, Gareth Owen

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

Abstract

The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.

Original language	English
Pages (from-to)	2782-2788
Journal	European Journal of Inorganic Chemistry
Volume	2013
Issue number	15
DOIs	https://doi.org/10.1002/ejic.201300106
Publication status	Published - 14 May 2013

Keywords

Rhodium
S ligands
Nitrogen heterocycles
Carbenes

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10.1002/ejic.201300106Licence: CC BY-NC-ND

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title = "Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors",

abstract = "The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.",

keywords = "Rhodium , S ligands, Nitrogen heterocycles , Carbenes",

author = "Miriam Slivarichova and Haddow, {Mairi F.} and Hafiizah Othman and Gareth Owen",

year = "2013",

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doi = "10.1002/ejic.201300106",

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T1 - Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors

AU - Slivarichova, Miriam

AU - Haddow, Mairi F.

AU - Othman, Hafiizah

AU - Owen, Gareth

PY - 2013/5/14

Y1 - 2013/5/14

N2 - The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.

AB - The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.

KW - Rhodium

KW - S ligands

KW - Nitrogen heterocycles

KW - Carbenes

U2 - 10.1002/ejic.201300106

DO - 10.1002/ejic.201300106

M3 - Article

SN - 1434-1948

VL - 2013

SP - 2782

EP - 2788

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 15

ER -

Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors

Abstract

Keywords

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