Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

Gareth R. Owen; Ramón Vilar; Andrew J.P. White; David J. Williams

doi:10.1021/om030235u

Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

Gareth R. Owen, Ramón Vilar^*, Andrew J.P. White, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η²-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η¹-imidoyl complex into the η²-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

Original language	English
Pages (from-to)	3025-3027
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	15
DOIs	https://doi.org/10.1021/om030235u
Publication status	Published - 21 Jul 2003
Externally published	Yes

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title = "Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif",

abstract = "The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.",

author = "Owen, {Gareth R.} and Ram{\'o}n Vilar and White, {Andrew J.P.} and Williams, {David J.}",

year = "2003",

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doi = "10.1021/om030235u",

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T1 - Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

AU - Owen, Gareth R.

AU - Vilar, Ramón

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2003/7/21

Y1 - 2003/7/21

N2 - The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

AB - The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

U2 - 10.1021/om030235u

DO - 10.1021/om030235u

M3 - Article

AN - SCOPUS:0041841293

SN - 0276-7333

VL - 22

SP - 3025

EP - 3027

JO - Organometallics

JF - Organometallics

IS - 15

ER -

Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

Abstract

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