Synthesis and structural characterisation of the palladium cluster compounds [Pd3(μ-SO2)2(μ-PPh 2py)2(PBz3)2] and [Pd 4(μ-SO2)2-(μ3-S)(CNR)(PBz 3)4] (R = tBu, 2,6-dimethylphenyl and cyclohexyl)

Anna M. Williamson; Gareth R. Owen; D. Michael P. Mingos; Ramón Vilar; Andrew J.P. White; David J. Williams

doi:10.1039/b302034g

Synthesis and structural characterisation of the palladium cluster compounds [Pd₃(μ-SO₂)₂(μ-PPh ₂py)₂(PBz₃)₂] and [Pd ₄(μ-SO₂)₂-(μ₃-S)(CNR)(PBz ₃)₄] (R = ^tBu, 2,6-dimethylphenyl and cyclohexyl)

Anna M. Williamson, Gareth R. Owen, D. Michael P. Mingos, Ramón Vilar^*, Andrew J.P. White, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We have reported previously that the reaction of [Pd₂(dba) ₃] (dba = dibenzylideneacetone) with PBz₃ in the presence of SO₂ yields [Pd₂(μ-SO₂)(μ-dba)(PBz ₃)₂] (1) and [Pd₃(μ-SO₂) ₃(PBz₃)₃] (2) (which can be prepared selectively by varying the concentration of SO₂). Here the reactions of 1 and 2 with PPh₂py (diphenylpyridine phosphine) to yield [Pd ₂(μ-SO₂)(μ-PPh₂py)(PBz₃) ₂] (4) and [Pd₃(μ-PPh₂py) ₂(μ-SO₂)₂(PBz₃)₂] (5), respectively, are reported. Structural characterisation of 5 shows it to be an unusual trimetallic compound. The reaction between the tetrahedral cluster [Pd₄(μ₃-S)(μ-SO₂) ₂(CO)(PBz₃)₄] (3) (which is prepared by reacting dimer 1 with COS) and CNR has also been studied. The isostructural clusters [Pd₄(μ₃-S)(μ-SO₂) ₂(CNR)(PBz₃)₄] (R = ^tBu, 6; CNCy, 7; CNXyl, 8; CNMe, 9) have been prepared and the structures of three of them are described here.

Original language	English
Pages (from-to)	2526-2532
Number of pages	7
Journal	Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/b302034g
Publication status	Published - 21 Jun 2003
Externally published	Yes

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10.1039/b302034gLicence: CC BY-NC-ND

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Williamson, A. M., Owen, G. R., Mingos, D. M. P., Vilar, R., White, A. J. P., & Williams, D. J. (2003). Synthesis and structural characterisation of the palladium cluster compounds [Pd₃(μ-SO₂)₂(μ-PPh ₂py)₂(PBz₃)₂] and [Pd ₄(μ-SO₂)₂-(μ₃-S)(CNR)(PBz ₃)₄] (R = ^tBu, 2,6-dimethylphenyl and cyclohexyl). Dalton Transactions, (12), 2526-2532. https://doi.org/10.1039/b302034g

@article{15126166d1254440b8c53acdf9997bf2,

title = "Synthesis and structural characterisation of the palladium cluster compounds [Pd3(μ-SO2)2(μ-PPh 2py)2(PBz3)2] and [Pd 4(μ-SO2)2-(μ3-S)(CNR)(PBz 3)4] (R = tBu, 2,6-dimethylphenyl and cyclohexyl)",

abstract = "We have reported previously that the reaction of [Pd2(dba) 3] (dba = dibenzylideneacetone) with PBz3 in the presence of SO2 yields [Pd2(μ-SO2)(μ-dba)(PBz 3)2] (1) and [Pd3(μ-SO2) 3(PBz3)3] (2) (which can be prepared selectively by varying the concentration of SO2). Here the reactions of 1 and 2 with PPh2py (diphenylpyridine phosphine) to yield [Pd 2(μ-SO2)(μ-PPh2py)(PBz3) 2] (4) and [Pd3(μ-PPh2py) 2(μ-SO2)2(PBz3)2] (5), respectively, are reported. Structural characterisation of 5 shows it to be an unusual trimetallic compound. The reaction between the tetrahedral cluster [Pd4(μ3-S)(μ-SO2) 2(CO)(PBz3)4] (3) (which is prepared by reacting dimer 1 with COS) and CNR has also been studied. The isostructural clusters [Pd4(μ3-S)(μ-SO2) 2(CNR)(PBz3)4] (R = tBu, 6; CNCy, 7; CNXyl, 8; CNMe, 9) have been prepared and the structures of three of them are described here.",

author = "Williamson, {Anna M.} and Owen, {Gareth R.} and Mingos, {D. Michael P.} and Ram{\'o}n Vilar and White, {Andrew J.P.} and Williams, {David J.}",

year = "2003",

month = jun,

day = "21",

doi = "10.1039/b302034g",

language = "English",

pages = "2526--2532",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "12",

}

Synthesis and structural characterisation of the palladium cluster compounds [Pd₃(μ-SO₂)₂(μ-PPh ₂py)₂(PBz₃)₂] and [Pd ₄(μ-SO₂)₂-(μ₃-S)(CNR)(PBz ₃)₄] (R = ^tBu, 2,6-dimethylphenyl and cyclohexyl). / Williamson, Anna M.; Owen, Gareth R.; Mingos, D. Michael P. et al.
In: Dalton Transactions, No. 12, 21.06.2003, p. 2526-2532.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and structural characterisation of the palladium cluster compounds [Pd3(μ-SO2)2(μ-PPh 2py)2(PBz3)2] and [Pd 4(μ-SO2)2-(μ3-S)(CNR)(PBz 3)4] (R = tBu, 2,6-dimethylphenyl and cyclohexyl)

AU - Williamson, Anna M.

AU - Owen, Gareth R.

AU - Mingos, D. Michael P.

AU - Vilar, Ramón

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2003/6/21

Y1 - 2003/6/21

N2 - We have reported previously that the reaction of [Pd2(dba) 3] (dba = dibenzylideneacetone) with PBz3 in the presence of SO2 yields [Pd2(μ-SO2)(μ-dba)(PBz 3)2] (1) and [Pd3(μ-SO2) 3(PBz3)3] (2) (which can be prepared selectively by varying the concentration of SO2). Here the reactions of 1 and 2 with PPh2py (diphenylpyridine phosphine) to yield [Pd 2(μ-SO2)(μ-PPh2py)(PBz3) 2] (4) and [Pd3(μ-PPh2py) 2(μ-SO2)2(PBz3)2] (5), respectively, are reported. Structural characterisation of 5 shows it to be an unusual trimetallic compound. The reaction between the tetrahedral cluster [Pd4(μ3-S)(μ-SO2) 2(CO)(PBz3)4] (3) (which is prepared by reacting dimer 1 with COS) and CNR has also been studied. The isostructural clusters [Pd4(μ3-S)(μ-SO2) 2(CNR)(PBz3)4] (R = tBu, 6; CNCy, 7; CNXyl, 8; CNMe, 9) have been prepared and the structures of three of them are described here.

AB - We have reported previously that the reaction of [Pd2(dba) 3] (dba = dibenzylideneacetone) with PBz3 in the presence of SO2 yields [Pd2(μ-SO2)(μ-dba)(PBz 3)2] (1) and [Pd3(μ-SO2) 3(PBz3)3] (2) (which can be prepared selectively by varying the concentration of SO2). Here the reactions of 1 and 2 with PPh2py (diphenylpyridine phosphine) to yield [Pd 2(μ-SO2)(μ-PPh2py)(PBz3) 2] (4) and [Pd3(μ-PPh2py) 2(μ-SO2)2(PBz3)2] (5), respectively, are reported. Structural characterisation of 5 shows it to be an unusual trimetallic compound. The reaction between the tetrahedral cluster [Pd4(μ3-S)(μ-SO2) 2(CO)(PBz3)4] (3) (which is prepared by reacting dimer 1 with COS) and CNR has also been studied. The isostructural clusters [Pd4(μ3-S)(μ-SO2) 2(CNR)(PBz3)4] (R = tBu, 6; CNCy, 7; CNXyl, 8; CNMe, 9) have been prepared and the structures of three of them are described here.

U2 - 10.1039/b302034g

DO - 10.1039/b302034g

M3 - Article

AN - SCOPUS:12344293679

SN - 1477-9226

SP - 2526

EP - 2532

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Synthesis and structural characterisation of the palladium cluster compounds [Pd3(μ-SO2)2(μ-PPh 2py)2(PBz3)2] and [Pd 4(μ-SO2)2-(μ3-S)(CNR)(PBz 3)4] (R = tBu, 2,6-dimethylphenyl and cyclohexyl)

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Synthesis and structural characterisation of the palladium cluster compounds [Pd₃(μ-SO₂)₂(μ-PPh ₂py)₂(PBz₃)₂] and [Pd ₄(μ-SO₂)₂-(μ₃-S)(CNR)(PBz ₃)₄] (R = ^tBu, 2,6-dimethylphenyl and cyclohexyl)