Sulfur oxidation mediated by imine derivatives

Philip C. Bulman Page; Donald Bethell; Paul A. Stocks; Jag P. Heer; Andrew E. Graham; Hooshang Vahedi; Mark Healy; Eric W. Collington; David M. Andrews

doi:10.1002/chin.199813090

Sulfur oxidation mediated by imine derivatives

Philip C. Bulman Page^*, Donald Bethell, Paul A. Stocks, Jag P. Heer, Andrew E. Graham, Hooshang Vahedi, Mark Healy, Eric W. Collington, David M. Andrews

^*Corresponding author for this work

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A number of oxime and benzothiazoline derivatives have been prepared and examined as mediators of sulfur oxidation by hydrogen peroxide as oxidant in the presence of base. In all cases, sulfoxidation was observed in the presence of the mediators, whereas negligible reaction occurred in the absence of mediator. Carbodiimides were also examined as mediators; they proved to be highly reactive, providing predominant oxidation directly to sulfone.

Original language	English
Pages (from-to)	1355-1358
Number of pages	4
Journal	Synlett
Issue number	12
DOIs	https://doi.org/10.1002/chin.199813090
Publication status	Published - Dec 1997

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@article{671b65c7b62a42f8885478f34a005b46,

title = "Sulfur oxidation mediated by imine derivatives",

abstract = "A number of oxime and benzothiazoline derivatives have been prepared and examined as mediators of sulfur oxidation by hydrogen peroxide as oxidant in the presence of base. In all cases, sulfoxidation was observed in the presence of the mediators, whereas negligible reaction occurred in the absence of mediator. Carbodiimides were also examined as mediators; they proved to be highly reactive, providing predominant oxidation directly to sulfone.",

author = "{Bulman Page}, {Philip C.} and Donald Bethell and Stocks, {Paul A.} and Heer, {Jag P.} and Graham, {Andrew E.} and Hooshang Vahedi and Mark Healy and Collington, {Eric W.} and Andrews, {David M.}",

year = "1997",

month = dec,

doi = "10.1002/chin.199813090",

language = "English",

pages = "1355--1358",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag KG",

number = "12",

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TY - JOUR

T1 - Sulfur oxidation mediated by imine derivatives

AU - Bulman Page, Philip C.

AU - Bethell, Donald

AU - Stocks, Paul A.

AU - Heer, Jag P.

AU - Graham, Andrew E.

AU - Vahedi, Hooshang

AU - Healy, Mark

AU - Collington, Eric W.

AU - Andrews, David M.

PY - 1997/12

Y1 - 1997/12

N2 - A number of oxime and benzothiazoline derivatives have been prepared and examined as mediators of sulfur oxidation by hydrogen peroxide as oxidant in the presence of base. In all cases, sulfoxidation was observed in the presence of the mediators, whereas negligible reaction occurred in the absence of mediator. Carbodiimides were also examined as mediators; they proved to be highly reactive, providing predominant oxidation directly to sulfone.

AB - A number of oxime and benzothiazoline derivatives have been prepared and examined as mediators of sulfur oxidation by hydrogen peroxide as oxidant in the presence of base. In all cases, sulfoxidation was observed in the presence of the mediators, whereas negligible reaction occurred in the absence of mediator. Carbodiimides were also examined as mediators; they proved to be highly reactive, providing predominant oxidation directly to sulfone.

U2 - 10.1002/chin.199813090

DO - 10.1002/chin.199813090

M3 - Article

AN - SCOPUS:26844567308

SN - 0936-5214

SP - 1355

EP - 1358

JO - Synlett

JF - Synlett

IS - 12

ER -

Sulfur oxidation mediated by imine derivatives

Abstract

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