Sulfur oxidation mediated by imine derivatives

Philip C. Bulman Page, Donald Bethell, Paul A. Stocks, Jag P. Heer, Andrew E. Graham, Hooshang Vahedi, Mark Healy, Eric W. Collington, David M. Andrews

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

A number of oxime and benzothiazoline derivatives have been prepared and examined as mediators of sulfur oxidation by hydrogen peroxide as oxidant in the presence of base. In all cases, sulfoxidation was observed in the presence of the mediators, whereas negligible reaction occurred in the absence of mediator. Carbodiimides were also examined as mediators; they proved to be highly reactive, providing predominant oxidation directly to sulfone.

Original languageEnglish
Pages (from-to)1355-1358
Number of pages4
JournalSynlett
Issue number12
DOIs
Publication statusPublished - Dec 1997

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