Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions

Gemma L. Brett; Qian He; Ceri Hammond; Peter J. Miedziak; Nikolaos Dimitratos; Meenakshisundaram Sankar; Andrew A. Herzing; Marco Conte; Jose Antonio Lopez-Sanchez; Christopher J. Kiely; Stuart H. Taylor; Graham J. Hutchings; David Knight

doi:10.1002/anie.201101772

Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions

Gemma L. Brett^*, Qian He, Ceri Hammond, Peter J. Miedziak, Nikolaos Dimitratos, Meenakshisundaram Sankar, Andrew A. Herzing, Marco Conte, Jose Antonio Lopez-Sanchez, Christopher J. Kiely, Stuart H. Taylor, Graham J. Hutchings, David Knight

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

142 Citations (Scopus)

Abstract

Au-Pt alloy nanoparticles deposited on Mg(OH) ₂ (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions.

Original language	English
Pages (from-to)	10136-10139
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	43
DOIs	https://doi.org/10.1002/anie.201101772
Publication status	Published - 17 Oct 2011
Externally published	Yes

Keywords

alloys
gold
heterogeneous catalysis
nanoparticles
platinum

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10.1002/anie.201101772Licence: CC BY-NC-ND

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Brett, G. L., He, Q., Hammond, C., Miedziak, P. J., Dimitratos, N., Sankar, M., Herzing, A. A., Conte, M., Lopez-Sanchez, J. A., Kiely, C. J., Taylor, S. H., Hutchings, G. J., & Knight, D. (2011). Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions. Angewandte Chemie - International Edition, 50(43), 10136-10139. https://doi.org/10.1002/anie.201101772

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title = "Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions",

abstract = "Au-Pt alloy nanoparticles deposited on Mg(OH) 2 (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions.",

keywords = "alloys, gold, heterogeneous catalysis, nanoparticles, platinum",

author = "Brett, {Gemma L.} and Qian He and Ceri Hammond and Miedziak, {Peter J.} and Nikolaos Dimitratos and Meenakshisundaram Sankar and Herzing, {Andrew A.} and Marco Conte and Lopez-Sanchez, {Jose Antonio} and Kiely, {Christopher J.} and Taylor, {Stuart H.} and Hutchings, {Graham J.} and David Knight",

year = "2011",

month = oct,

day = "17",

doi = "10.1002/anie.201101772",

language = "English",

volume = "50",

pages = "10136--10139",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "Wiley",

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Brett, GL, He, Q, Hammond, C, Miedziak, PJ, Dimitratos, N, Sankar, M, Herzing, AA, Conte, M, Lopez-Sanchez, JA, Kiely, CJ, Taylor, SH, Hutchings, GJ & Knight, D 2011, 'Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions', Angewandte Chemie - International Edition, vol. 50, no. 43, pp. 10136-10139. https://doi.org/10.1002/anie.201101772

TY - JOUR

T1 - Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions

AU - Brett, Gemma L.

AU - He, Qian

AU - Hammond, Ceri

AU - Miedziak, Peter J.

AU - Dimitratos, Nikolaos

AU - Sankar, Meenakshisundaram

AU - Herzing, Andrew A.

AU - Conte, Marco

AU - Lopez-Sanchez, Jose Antonio

AU - Kiely, Christopher J.

AU - Taylor, Stuart H.

AU - Hutchings, Graham J.

AU - Knight, David

PY - 2011/10/17

Y1 - 2011/10/17

N2 - Au-Pt alloy nanoparticles deposited on Mg(OH) 2 (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions.

AB - Au-Pt alloy nanoparticles deposited on Mg(OH) 2 (see STEM-HAADF image) show high activity in the selective oxidation of polyols using molecular oxygen as oxidant at mild and base-free conditions.

KW - alloys

KW - gold

KW - heterogeneous catalysis

KW - nanoparticles

KW - platinum

U2 - 10.1002/anie.201101772

DO - 10.1002/anie.201101772

M3 - Article

C2 - 21990249

AN - SCOPUS:80054047205

SN - 1433-7851

VL - 50

SP - 10136

EP - 10139

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 43

ER -

Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions

Abstract

Keywords

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