Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions

Rosenildo  Da Costa; Thierry Buffeteau; André  Del Guerzo; Nathan D.  McClenaghan; Jean-Marc Vincent

doi:10.1039/C1CC12641E

Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)₃]²⁺ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions

Rosenildo Da Costa, Thierry Buffeteau, André Del Guerzo, Nathan D. McClenaghan, Jean-Marc Vincent

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

Abstract

The Ru(bipy)₃ dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate–carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production

Original language	English
Pages (from-to)	8250–8252
Journal	Chemical Communications
Volume	47
DOIs	https://doi.org/10.1039/C1CC12641E
Publication status	Published - 2011

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10.1039/C1CC12641ELicence: CC BY-NC-ND

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title = "Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions",

abstract = "The Ru(bipy)3 dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate–carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production",

author = "{Da Costa}, Rosenildo and Thierry Buffeteau and {Del Guerzo}, Andr{\'e} and McClenaghan, {Nathan D.} and Jean-Marc Vincent",

year = "2011",

doi = "10.1039/C1CC12641E",

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AU - Da Costa, Rosenildo

AU - Buffeteau, Thierry

AU - Del Guerzo, André

AU - McClenaghan, Nathan D.

AU - Vincent, Jean-Marc

PY - 2011

Y1 - 2011

N2 - The Ru(bipy)3 dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate–carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production

AB - The Ru(bipy)3 dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate–carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production

U2 - 10.1039/C1CC12641E

DO - 10.1039/C1CC12641E

M3 - Article

SN - 1359-7345

VL - 47

SP - 8250

EP - 8252

JO - Chemical Communications

JF - Chemical Communications

ER -

Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions

Abstract

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Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)₃]²⁺ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions