Polyazolyl chelate chemistry. 12.1 An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

Mark R.St J. Foreman; Anthony F. Hill; Gareth R. Owen; Andrew J.P. White; David J. Williams

doi:10.1021/om030550g

Polyazolyl chelate chemistry. 12.¹ An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

Mark R.St J. Foreman, Anthony F. Hill^*, Gareth R. Owen, Andrew J.P. White, David J. Williams

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

The reactions of [RuHCl(CO)(PPh₃)₃] or [RuH(NCMe)₂(CO)(PPh₃)₂]ClO₄ with Na[HB(mt)₃] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh₃){κ³-H,S,S″-HB(mt)₃}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh₃){B(mt)₃}](Ru→B).

Original language	English
Pages (from-to)	4446-4450
Number of pages	5
Journal	Organometallics
Volume	22
Issue number	22
DOIs	https://doi.org/10.1021/om030550g
Publication status	Published - 27 Oct 2003
Externally published	Yes

Access to Document

10.1021/om030550gLicence: CC BY-NC-ND

Cite this

@article{b27e31245296490b8b19ad522b8f37bb,

title = "Polyazolyl chelate chemistry. 12.1 An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand",

abstract = "The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)3}](Ru→B).",

author = "Foreman, {Mark R.St J.} and Hill, {Anthony F.} and Owen, {Gareth R.} and White, {Andrew J.P.} and Williams, {David J.}",

year = "2003",

month = oct,

day = "27",

doi = "10.1021/om030550g",

language = "English",

volume = "22",

pages = "4446--4450",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Polyazolyl chelate chemistry. 12.1 An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

AU - Foreman, Mark R.St J.

AU - Hill, Anthony F.

AU - Owen, Gareth R.

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2003/10/27

Y1 - 2003/10/27

N2 - The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)3}](Ru→B).

AB - The reactions of [RuHCl(CO)(PPh3)3] or [RuH(NCMe)2(CO)(PPh3)2]ClO4 with Na[HB(mt)3] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){κ3-H,S,S″-HB(mt)3}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)3}](Ru→B).

U2 - 10.1021/om030550g

DO - 10.1021/om030550g

M3 - Article

AN - SCOPUS:0344493889

SN - 0276-7333

VL - 22

SP - 4446

EP - 4450

JO - Organometallics

JF - Organometallics

IS - 22

ER -

Polyazolyl chelate chemistry. 12.1 An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

Abstract

Access to Document

Fingerprint

Cite this

Polyazolyl chelate chemistry. 12.¹ An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand