Physical mixing of metal acetates: Optimisation of catalyst parameters to produce highly active bimetallic catalysts

Peter J. Miedziak; Simon A. Kondrat; Noreen Sajjad; Gavin M. King; Mark Douthwaite; Greg Shaw; Gemma L. Brett; Jennifer K. Edwards; David J. Morgan; Ghulam Hussain; Graham J. Hutchings

doi:10.1039/c3cy00263b

Physical mixing of metal acetates: Optimisation of catalyst parameters to produce highly active bimetallic catalysts

Peter J. Miedziak, Simon A. Kondrat, Noreen Sajjad, Gavin M. King, Mark Douthwaite, Greg Shaw, Gemma L. Brett, Jennifer K. Edwards, David J. Morgan, Ghulam Hussain, Graham J. Hutchings^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.

Original language	English
Pages (from-to)	2910-2917
Number of pages	8
Journal	Catalysis Science and Technology
Volume	3
Issue number	11
DOIs	https://doi.org/10.1039/c3cy00263b
Publication status	Published - 1 Oct 2013
Externally published	Yes

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Miedziak, P. J., Kondrat, S. A., Sajjad, N., King, G. M., Douthwaite, M., Shaw, G., Brett, G. L., Edwards, J. K., Morgan, D. J., Hussain, G., & Hutchings, G. J. (2013). Physical mixing of metal acetates: Optimisation of catalyst parameters to produce highly active bimetallic catalysts. Catalysis Science and Technology, 3(11), 2910-2917. https://doi.org/10.1039/c3cy00263b

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title = "Physical mixing of metal acetates: Optimisation of catalyst parameters to produce highly active bimetallic catalysts",

abstract = "We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.",

author = "Miedziak, {Peter J.} and Kondrat, {Simon A.} and Noreen Sajjad and King, {Gavin M.} and Mark Douthwaite and Greg Shaw and Brett, {Gemma L.} and Edwards, {Jennifer K.} and Morgan, {David J.} and Ghulam Hussain and Hutchings, {Graham J.}",

year = "2013",

month = oct,

day = "1",

doi = "10.1039/c3cy00263b",

language = "English",

volume = "3",

pages = "2910--2917",

journal = "Catalysis Science and Technology",

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T1 - Physical mixing of metal acetates

T2 - Optimisation of catalyst parameters to produce highly active bimetallic catalysts

AU - Miedziak, Peter J.

AU - Kondrat, Simon A.

AU - Sajjad, Noreen

AU - King, Gavin M.

AU - Douthwaite, Mark

AU - Shaw, Greg

AU - Brett, Gemma L.

AU - Edwards, Jennifer K.

AU - Morgan, David J.

AU - Hussain, Ghulam

AU - Hutchings, Graham J.

PY - 2013/10/1

Y1 - 2013/10/1

N2 - We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.

AB - We have investigated the optimisation of the catalytic parameters for the preparation of catalysts by the simple mixing and thermal treatment of a support and metal acetate precursors. We have studied the effect of metal ratio and metal loading to produce a catalyst which has the optimum activity for a variety of reactions including benzyl alcohol oxidation, glycerol oxidation and the direct synthesis of hydrogen peroxide. We have demonstrated the high activity of these catalyst's for a variety of substrates and performed XPS and XRD studies on the catalysts to help elucidate the origin of the catalysts improved activity.

U2 - 10.1039/c3cy00263b

DO - 10.1039/c3cy00263b

M3 - Article

AN - SCOPUS:84885626169

VL - 3

SP - 2910

EP - 2917

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 11

ER -

Physical mixing of metal acetates: Optimisation of catalyst parameters to produce highly active bimetallic catalysts

Abstract

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