Episulfone α-anions: Preparation and synthetic applications

Andrew E. Graham; Wendy A. Loughlin; Richard J K Taylor

doi:10.1016/0040-4039(94)85382-7

Episulfone α-anions: Preparation and synthetic applications

Andrew E. Graham^*, Wendy A. Loughlin, Richard J K Taylor

^*Corresponding author for this work

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone α-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

Original language	English
Pages (from-to)	7281-7284
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	39
DOIs	https://doi.org/10.1016/0040-4039(94)85382-7
Publication status	Published - 26 Sept 1994

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title = "Episulfone α-anions: Preparation and synthetic applications",

abstract = "Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone α-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes. ",

author = "Graham, {Andrew E.} and Loughlin, {Wendy A.} and Taylor, {Richard J K}",

year = "1994",

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T1 - Episulfone α-anions

T2 - Preparation and synthetic applications

AU - Graham, Andrew E.

AU - Loughlin, Wendy A.

AU - Taylor, Richard J K

PY - 1994/9/26

Y1 - 1994/9/26

N2 - Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone α-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

AB - Monosilyl-, monostannyl-, disilyl- and distannyl-episulfones have been prepared by episulfone α-anion generation followed by trapping with the appropriate electrophilic reagent. Elimination of sulfur dioxide provides a new route for the preparation of vinyl silanes and vinyl stannanes.

U2 - 10.1016/0040-4039(94)85382-7

DO - 10.1016/0040-4039(94)85382-7

M3 - Article

AN - SCOPUS:0027978884

SN - 1873-3581

VL - 35

SP - 7281

EP - 7284

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 39

ER -

Episulfone α-anions: Preparation and synthetic applications

Abstract

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