Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

David Antonelli; Hung V. Mai; Tuan K.A. Hoang; Ahmad Hamaed; Michel Trudeau

doi:10.1039/c001964j

Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

David Antonelli, Hung V. Mai, Tuan K.A. Hoang, Ahmad Hamaed, Michel Trudeau

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

Abstract

Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

Original language	English
Pages (from-to)	3206 - 3208
Number of pages	2
Journal	Chemistry Communications
Volume	46
DOIs	https://doi.org/10.1039/c001964j
Publication status	Published - 1 Jan 2010

Keywords

kubas-type
hydrogen storage

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10.1039/c001964jLicence: CC BY-NC-ND

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title = "Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage",

abstract = "Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.",

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AU - Antonelli, David

AU - Mai, Hung V.

AU - Hoang, Tuan K.A.

AU - Hamaed, Ahmad

AU - Trudeau, Michel

PY - 2010/1/1

Y1 - 2010/1/1

N2 - Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

AB - Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

KW - kubas-type

KW - hydrogen storage

U2 - 10.1039/c001964j

DO - 10.1039/c001964j

M3 - Article

C2 - 20424775

VL - 46

SP - 3206

EP - 3208

JO - Chemistry Communications

JF - Chemistry Communications

ER -

Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

Abstract

Keywords

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