Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

Mathew W. C. Robinson; Kathryn S. Pillinger; Ian Mabbett; David A. Timms; Andrew E. Graham

doi:10.1016/j.tet.2010.08.078

Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

Mathew W. C. Robinson, Kathryn S. Pillinger, Ian Mabbett, David A. Timms, Andrew E. Graham

Faculty of Computing, Engineering and Science

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

Original language	English
Pages (from-to)	8377-8382
Number of pages	6
Journal	Tetrahedron Letters
Volume	66
Issue number	43
DOIs	https://doi.org/10.1016/j.tet.2010.08.078
Publication status	Published - 23 Oct 2010

Keywords

Copper(II) tetrafluoroborate
Lewis acid catalyst
Meinwald rearrangement
Nanoporous aluminosilicates

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10.1016/j.tet.2010.08.078Licence: CC BY-NC-ND

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abstract = "Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed. ",

keywords = "Copper(II) tetrafluoroborate, Lewis acid catalyst, Meinwald rearrangement, Nanoporous aluminosilicates",

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AU - Robinson, Mathew W. C.

AU - Pillinger, Kathryn S.

AU - Mabbett, Ian

AU - Timms, David A.

AU - Graham, Andrew E.

PY - 2010/10/23

Y1 - 2010/10/23

N2 - Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

AB - Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

KW - Copper(II) tetrafluoroborate

KW - Lewis acid catalyst

KW - Meinwald rearrangement

KW - Nanoporous aluminosilicates

U2 - 10.1016/j.tet.2010.08.078

DO - 10.1016/j.tet.2010.08.078

M3 - Article

AN - SCOPUS:77957337153

VL - 66

SP - 8377

EP - 8382

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 43

ER -

Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

Abstract

Keywords

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