Analysis induced reduction of a polyelectrolyte

Rachel L. McLaren; Gareth R. Owen; David J. Morgan

doi:10.1016/j.rsurfi.2021.100032

Analysis induced reduction of a polyelectrolyte

Rachel L. McLaren, Gareth R. Owen, David J. Morgan

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Abstract

The polymer, poly(diallyldimethylammonium chloride) (PDDA), is shown to undergo chemical change via a reduction mechanism during X-ray analysis. Examination of the N 1s spectrum of PDDA shows a time dependence on the degree of reduction, together with clear amplification of the extent of reduction through the charge compensation system and X-ray irradiation.

Original language	English
Article number	100032
Number of pages	5
Journal	Results in Surfaces and Interfaces
Volume	6
Early online date	5 Dec 2021
DOIs	https://doi.org/10.1016/j.rsurfi.2021.100032
Publication status	Published - 1 Feb 2022

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title = "Analysis induced reduction of a polyelectrolyte",

abstract = "The polymer, poly(diallyldimethylammonium chloride) (PDDA), is shown to undergo chemical change via a reduction mechanism during X-ray analysis. Examination of the N 1s spectrum of PDDA shows a time dependence on the degree of reduction, together with clear amplification of the extent of reduction through the charge compensation system and X-ray irradiation.",

author = "McLaren, {Rachel L.} and Owen, {Gareth R.} and Morgan, {David J.}",

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AU - McLaren, Rachel L.

AU - Owen, Gareth R.

AU - Morgan, David J.

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N2 - The polymer, poly(diallyldimethylammonium chloride) (PDDA), is shown to undergo chemical change via a reduction mechanism during X-ray analysis. Examination of the N 1s spectrum of PDDA shows a time dependence on the degree of reduction, together with clear amplification of the extent of reduction through the charge compensation system and X-ray irradiation.

AB - The polymer, poly(diallyldimethylammonium chloride) (PDDA), is shown to undergo chemical change via a reduction mechanism during X-ray analysis. Examination of the N 1s spectrum of PDDA shows a time dependence on the degree of reduction, together with clear amplification of the extent of reduction through the charge compensation system and X-ray irradiation.

U2 - 10.1016/j.rsurfi.2021.100032

DO - 10.1016/j.rsurfi.2021.100032

M3 - Article

SN - 2666-8459

VL - 6

JO - Results in Surfaces and Interfaces

JF - Results in Surfaces and Interfaces

M1 - 100032

ER -

Analysis induced reduction of a polyelectrolyte

Abstract

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