A new family of metallaboratrane complexes based on 7-azaindole:  B-H activation mediated by carbon monoxide

Nikolaos Tsoureas; Mairi F. Haddow; Alex Hamilton; Gareth R. Owen

doi:10.1039/b822678d

A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Nikolaos Tsoureas, Mairi F. Haddow, Alex Hamilton, Gareth R. Owen

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl) ₃}^-] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

Original language	English
Pages (from-to)	2538-2540
Number of pages	3
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/b822678d
Publication status	Published - 5 May 2009
Externally published	Yes

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title = "A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide",

abstract = "The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl) 3}-] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.",

author = "Nikolaos Tsoureas and Haddow, {Mairi F.} and Alex Hamilton and Owen, {Gareth R.}",

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T2 - B-H activation mediated by carbon monoxide

AU - Tsoureas, Nikolaos

AU - Haddow, Mairi F.

AU - Hamilton, Alex

AU - Owen, Gareth R.

PY - 2009/5/5

Y1 - 2009/5/5

N2 - The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl) 3}-] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

AB - The reaction of Ir(COD)(Tai) [where Tai = {HB(7-azaindoyl) 3}-] with carbon monoxide results, via a sequence of hydride migration and insertion steps, in the formation of the first complexes to contain a metal-to-boron dative interaction supported by 7-azaindole units.

U2 - 10.1039/b822678d

DO - 10.1039/b822678d

M3 - Article

AN - SCOPUS:65349119966

SN - 1359-7345

SP - 2538

EP - 2540

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

A new family of metallaboratrane complexes based on 7-azaindole: B-H activation mediated by carbon monoxide

Abstract

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