TY - JOUR
T1 - A Comprehensive Performance Evaluation of GGBS-Based Geopolymer Concrete Activated by a Rice Husk Ash-Synthesised Sodium Silicate Solution and Sodium Hydroxide
AU - Oti, Jonathan
AU - Adeleke, Blessing O.
AU - Mudiyanselage, Prageeth R.
AU - Kinuthia, John
N1 - Not yet listed in press <https://www.mdpi.com/search?q=&journal=recycling&sort=pubdate&page_count=50> GM 12.3.24
PY - 2024/3/14
Y1 - 2024/3/14
N2 - Commercial sodium hydroxide (NaOH) and sodium silicate (SS) are commonly used as alkaline activators in geopolymer concrete production despite concerns about their availability and associated CO2 emissions. This study employs an alternative alkaline activator (AA) synthesized from a sodium silicate alternative (SSA) solution derived from rice husk ash (RHA) and a 10 M sodium hydroxide solution. The initial phase established an optimal water-to-binder (W/B) ratio of 0.50, balancing workability and structural performance. Subsequent investigations explored the influence of the alkali/precursor (A/P) ratio on geopolymer concrete properties. A control mix uses ordinary Portland cement (OPC), while ground granulated blast-furnace slag (GGBS)-based geopolymer concrete—GPC mixes (GPC1, GPC2, GPC3, GPC4) vary the A/P ratios (0.2, 0.4, 0.6, 0.8) with a 1:1 ratio of sodium silicate to sodium hydroxide (SS: SH). The engineering performance was evaluated through a slump test, and unconfined compressive strength (UCS) and tensile splitting (TS) tests in accordance with the appropriate standards. The geopolymer mixes, excluding GPC3, offer suitable workability; UCS and TS, though lower than the control mix, peak at an A/P ratio of 0.4. Despite lower mechanical strength than OPC, geopolymers’ environmental benefits make them a valuable alternative. GPC2, with a 0.4 A/P ratio and 0.5 W/B (water to binder) ratio, is recommended for balanced workability and structural performance. Future research should focus on enhancing the mechanical properties of geopolymer concrete for sustainable, high-performance mixtures.
AB - Commercial sodium hydroxide (NaOH) and sodium silicate (SS) are commonly used as alkaline activators in geopolymer concrete production despite concerns about their availability and associated CO2 emissions. This study employs an alternative alkaline activator (AA) synthesized from a sodium silicate alternative (SSA) solution derived from rice husk ash (RHA) and a 10 M sodium hydroxide solution. The initial phase established an optimal water-to-binder (W/B) ratio of 0.50, balancing workability and structural performance. Subsequent investigations explored the influence of the alkali/precursor (A/P) ratio on geopolymer concrete properties. A control mix uses ordinary Portland cement (OPC), while ground granulated blast-furnace slag (GGBS)-based geopolymer concrete—GPC mixes (GPC1, GPC2, GPC3, GPC4) vary the A/P ratios (0.2, 0.4, 0.6, 0.8) with a 1:1 ratio of sodium silicate to sodium hydroxide (SS: SH). The engineering performance was evaluated through a slump test, and unconfined compressive strength (UCS) and tensile splitting (TS) tests in accordance with the appropriate standards. The geopolymer mixes, excluding GPC3, offer suitable workability; UCS and TS, though lower than the control mix, peak at an A/P ratio of 0.4. Despite lower mechanical strength than OPC, geopolymers’ environmental benefits make them a valuable alternative. GPC2, with a 0.4 A/P ratio and 0.5 W/B (water to binder) ratio, is recommended for balanced workability and structural performance. Future research should focus on enhancing the mechanical properties of geopolymer concrete for sustainable, high-performance mixtures.
KW - alternative alkaline activator
KW - sodium silicate alternative
KW - rice husk ash
KW - GGBS
KW - geopolymer
KW - unconfined compressive strength
KW - tensile strength
KW - alkali/precursor (A/P) ratio
KW - commercial sodium hydroxide
KW - sodium silicate
U2 - https://doi.org/10.3390/recycling9020023
DO - https://doi.org/10.3390/recycling9020023
M3 - Article
SN - 2313-4321
VL - 9
SP - 1
EP - 14
JO - Recycling
JF - Recycling
IS - 2
M1 - 23
ER -