The sting of the scorpion: A metallaboratrane

Anthony F. Hill; Gareth R. Owen; Andrew J.P. White; David J. Williams

doi:10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P

The sting of the scorpion: A metallaboratrane

Anthony F. Hill^*, Gareth R. Owen, Andrew J.P. White, David J. Williams

^*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

271 Dyfyniadau (Scopus)

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An unprecedented intramolecular B-H activation of a hydrotris(2- sulfanyl-1-methylimidazolyl)borate ligand coordinated to ruthenium has provided the first example of metallaboratranes. The remarkable ease with which the ruthenaboratrane 1 forms relative to the case with a hydrotris(pyrazolyl)borate ligand is a consequence of the lability of the chelation and the increased ring size of the chelates.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	2759-2761
Nifer y tudalennau	3
Cyfnodolyn	Angewandte Chemie - International Edition
Cyfrol	38
Rhif cyhoeddi	18
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P
Statws	Cyhoeddwyd - 17 Medi 1999
Cyhoeddwyd yn allanol	Ie

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10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-PTrwydded: CC BY-NC-ND

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title = "The sting of the scorpion: A metallaboratrane",

abstract = "An unprecedented intramolecular B-H activation of a hydrotris(2- sulfanyl-1-methylimidazolyl)borate ligand coordinated to ruthenium has provided the first example of metallaboratranes. The remarkable ease with which the ruthenaboratrane 1 forms relative to the case with a hydrotris(pyrazolyl)borate ligand is a consequence of the lability of the chelation and the increased ring size of the chelates.",

keywords = "Boratrane, Boron, N ligands, Ruthenium",

author = "Hill, {Anthony F.} and Owen, {Gareth R.} and White, {Andrew J.P.} and Williams, {David J.}",

year = "1999",

month = sep,

day = "17",

doi = "10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P",

language = "English",

volume = "38",

pages = "2759--2761",

journal = "Angewandte Chemie International Edition",

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TY - JOUR

T1 - The sting of the scorpion

T2 - A metallaboratrane

AU - Hill, Anthony F.

AU - Owen, Gareth R.

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 1999/9/17

Y1 - 1999/9/17

N2 - An unprecedented intramolecular B-H activation of a hydrotris(2- sulfanyl-1-methylimidazolyl)borate ligand coordinated to ruthenium has provided the first example of metallaboratranes. The remarkable ease with which the ruthenaboratrane 1 forms relative to the case with a hydrotris(pyrazolyl)borate ligand is a consequence of the lability of the chelation and the increased ring size of the chelates.

AB - An unprecedented intramolecular B-H activation of a hydrotris(2- sulfanyl-1-methylimidazolyl)borate ligand coordinated to ruthenium has provided the first example of metallaboratranes. The remarkable ease with which the ruthenaboratrane 1 forms relative to the case with a hydrotris(pyrazolyl)borate ligand is a consequence of the lability of the chelation and the increased ring size of the chelates.

KW - Boratrane

KW - Boron

KW - N ligands

KW - Ruthenium

U2 - 10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P

DO - 10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P

M3 - Article

AN - SCOPUS:0033578646

VL - 38

SP - 2759

EP - 2761

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 18

ER -

The sting of the scorpion: A metallaboratrane

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