The roles of Lewis acids in nickel catalysis

Benjamin S. Grills; Benjamin N. Bnawal; Gareth Owen; Nildo Costa

The roles of Lewis acids in nickel catalysis

Benjamin S. Grills^*, Benjamin N. Bnawal^*, Gareth Owen (Golygydd), Nildo Costa (Golygydd)

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Due to the global demand for more sustainable chemical production, Ni-catalysis has attracted significant attention, leading to the discovery of a plethora of powerful synthetic transformations. However, the mechanisms by which these transformations occur are still shrouded in mystery and poorly understood. In particular, the roles that Lewis acids can undertake in Ni-catalysis can often complicate the mechanistic picture. Herein, we discuss several examples that demonstrate the beneficial, and detrimental, effects Lewis acids can have in Ni-catalysis.

Iaith wreiddiol	Saesneg
Teitl	Organometallic Chemistry: Volume 45
Golygyddion	Clare Bakewell, Nildo Costa, Rebecca Musgrave, Gareth Owen
Cyhoeddwr	Royal Society of Chemistry
Pennod	3
Tudalennau	73 - 92
Cyfrol	45
ISBN (Electronig)	978-1-83767-619-4 , 978-1-83767-620-0
ISBN (Argraffiad)	978-1-83767-461-9
Statws	Cyhoeddwyd - 6 Rhag 2024

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Enw	Organometallic Chemistry
Cyhoeddwr	Royal Society of Chemistry
Cyfrol	45
ISSN (Argraffiad)	0301-0074
ISSN (Electronig)	1465-1890

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Organometallic Chemistry: Volume 45: Specialist Periodical Reports - Organometallic Chemistry
Bakewell, C. (gol.), Costa, N. (gol.), Musgrave, R. (gol.) & Owen, G. (gol.), 6 Rhag 2024, Royal Society of Chemistry. 340 t. (Organometallic Chemistry; Cyfrol 45)
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title = "The roles of Lewis acids in nickel catalysis",

abstract = "Due to the global demand for more sustainable chemical production, Ni-catalysis has attracted significant attention, leading to the discovery of a plethora of powerful synthetic transformations. However, the mechanisms by which these transformations occur are still shrouded in mystery and poorly understood. In particular, the roles that Lewis acids can undertake in Ni-catalysis can often complicate the mechanistic picture. Herein, we discuss several examples that demonstrate the beneficial, and detrimental, effects Lewis acids can have in Ni-catalysis.",

keywords = "Homogeneous Catalysis, Lewis acids, Transition metals",

author = "Grills, {Benjamin S.} and Bnawal, {Benjamin N.} and Gareth Owen and Nildo Costa",

year = "2024",

month = dec,

day = "6",

language = "English",

isbn = "978-1-83767-461-9",

volume = "45",

series = "Organometallic Chemistry",

publisher = "Royal Society of Chemistry",

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editor = "Clare Bakewell and Nildo Costa and Rebecca Musgrave and Gareth Owen",

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The roles of Lewis acids in nickel catalysis. / Grills, Benjamin S.; Bnawal, Benjamin N.; Owen, Gareth (Golygydd) et al.
Organometallic Chemistry: Volume 45. gol. / Clare Bakewell; Nildo Costa; Rebecca Musgrave; Gareth Owen. Cyfrol 45 Royal Society of Chemistry, 2024. t. 73 - 92 (Organometallic Chemistry; Cyfrol 45).

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TY - CHAP

T1 - The roles of Lewis acids in nickel catalysis

AU - Grills, Benjamin S.

AU - Bnawal, Benjamin N.

A2 - Owen, Gareth

A2 - Costa, Nildo

A2 - Bakewell, Clare

A2 - Costa, Nildo

A2 - Musgrave, Rebecca

A2 - Owen, Gareth

PY - 2024/12/6

Y1 - 2024/12/6

N2 - Due to the global demand for more sustainable chemical production, Ni-catalysis has attracted significant attention, leading to the discovery of a plethora of powerful synthetic transformations. However, the mechanisms by which these transformations occur are still shrouded in mystery and poorly understood. In particular, the roles that Lewis acids can undertake in Ni-catalysis can often complicate the mechanistic picture. Herein, we discuss several examples that demonstrate the beneficial, and detrimental, effects Lewis acids can have in Ni-catalysis.

AB - Due to the global demand for more sustainable chemical production, Ni-catalysis has attracted significant attention, leading to the discovery of a plethora of powerful synthetic transformations. However, the mechanisms by which these transformations occur are still shrouded in mystery and poorly understood. In particular, the roles that Lewis acids can undertake in Ni-catalysis can often complicate the mechanistic picture. Herein, we discuss several examples that demonstrate the beneficial, and detrimental, effects Lewis acids can have in Ni-catalysis.

KW - Homogeneous Catalysis

KW - Lewis acids

KW - Transition metals

M3 - Chapter

SN - 978-1-83767-461-9

VL - 45

T3 - Organometallic Chemistry

SP - 73

EP - 92

BT - Organometallic Chemistry: Volume 45

PB - Royal Society of Chemistry

ER -

The roles of Lewis acids in nickel catalysis

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Organometallic Chemistry: Volume 45: Specialist Periodical Reports - Organometallic Chemistry

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