Crynodeb
The reaction of [Ru(CH=CH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh 3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt) 3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = tBu, C6H 3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh 3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}J, [Ru(CO)(CN tBu)({B(mt)3)], and [Ru(CO)(CNC6H 2Me3-2,4,6){B(mt)3}] are reported.
Iaith wreiddiol | Saesneg |
---|---|
Tudalennau (o-i) | 381-386 |
Nifer y tudalennau | 6 |
Cyfnodolyn | Organometallics |
Cyfrol | 27 |
Rhif cyhoeddi | 3 |
Dynodwyr Gwrthrych Digidol (DOIs) | |
Statws | Cyhoeddwyd - 11 Chwef 2008 |
Cyhoeddwyd yn allanol | Ie |