Synthesis of the ruthenaboratranes [Ru(CS)(PPh3){B(mt) 3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}] (Ru→B)8 (mt = methimazolyl, R = tBu, C 6H3Me2-2,6, C6H2Me 3-2,4,6)

Ian R. Crossley, Mark R.St J. Foreman, Anthony F. Hill*, Gareth R. Owen, Andrew J.P. White, David J. Williams, Anthony C. Willis

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

62 Dyfyniadau (Scopus)

Crynodeb

The reaction of [Ru(CH=CH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh 3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt) 3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = tBu, C6H 3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh 3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}J, [Ru(CO)(CN tBu)({B(mt)3)], and [Ru(CO)(CNC6H 2Me3-2,4,6){B(mt)3}] are reported.

Iaith wreiddiolSaesneg
Tudalennau (o-i)381-386
Nifer y tudalennau6
CyfnodolynOrganometallics
Cyfrol27
Rhif cyhoeddi3
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 11 Chwef 2008
Cyhoeddwyd yn allanolIe

Ôl bys

Gweld gwybodaeth am bynciau ymchwil 'Synthesis of the ruthenaboratranes [Ru(CS)(PPh3){B(mt) 3}](Ru→B)8 and [Ru(CO)(CNR){B(mt)3}] (Ru→B)8 (mt = methimazolyl, R = tBu, C 6H3Me2-2,6, C6H2Me 3-2,4,6)'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

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