TY - JOUR
T1 - Synthesis and Structural Characterization of Rhodium Complexes Featuring Ditopic N-Heterocyclic Carbene/Thione Donors
AU - Slivarichova, Miriam
AU - Haddow, Mairi F.
AU - Othman, Hafiizah
AU - Owen, Gareth
PY - 2013/5/14
Y1 - 2013/5/14
N2 - The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.
AB - The N-heterocyclic carbene NHC/thione ligand precursors 1-[(3-R-2-thioxo-2H-imidazol-1-yl)methyl]-3-R-2H-imidazol-2-ium hexafluorophosphate, [HCSR]PF6 (R = methyl, benzyl) have been prepared and used in the synthesis of the complexes [Rh(CSR)(cod)][PF6] (R = methyl, benzyl; cod = 1,5-cyclooctadiene). The coordination and structural features of the novel ditopic NHC/thione ligands have been explored.
KW - Rhodium
KW - S ligands
KW - Nitrogen heterocycles
KW - Carbenes
U2 - 10.1002/ejic.201300106
DO - 10.1002/ejic.201300106
M3 - Article
VL - 2013
SP - 2782
EP - 2788
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
SN - 1434-1948
IS - 15
ER -