Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

Gareth R. Owen; Ramón Vilar; Andrew J.P. White; David J. Williams

doi:10.1021/om030235u

Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

Gareth R. Owen, Ramón Vilar^*, Andrew J.P. White, David J. Williams

^*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

15 Dyfyniadau (Scopus)

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The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η²-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η¹-imidoyl complex into the η²-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	3025-3027
Nifer y tudalennau	3
Cyfnodolyn	Organometallics
Cyfrol	22
Rhif cyhoeddi	15
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1021/om030235u
Statws	Cyhoeddwyd - 21 Gorff 2003
Cyhoeddwyd yn allanol	Ie

Mynediad at Ddogfen

10.1021/om030235uTrwydded: CC BY-NC-ND

Dyfynnu hyn

@article{f9730c1957a24bada70ab3e97f3d5535,

title = "Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif",

abstract = "The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.",

author = "Owen, {Gareth R.} and Ram{\'o}n Vilar and White, {Andrew J.P.} and Williams, {David J.}",

year = "2003",

month = jul,

day = "21",

doi = "10.1021/om030235u",

language = "English",

volume = "22",

pages = "3025--3027",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

AU - Owen, Gareth R.

AU - Vilar, Ramón

AU - White, Andrew J.P.

AU - Williams, David J.

PY - 2003/7/21

Y1 - 2003/7/21

N2 - The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

AB - The reactivity of palladium-imidoyl complexes with imines was studied. Investigations showed the formation of a novel dipalladium complex, with one of the palladium centers being η2-coordinated to an imidoyl group. The mechanism of the process was believed to involve a transformation of the η1-imidoyl complex into the η2-imidoyl species, followed by a Pd-C bond cleavage and a dimerization process via formation of new C-C and Pd-N bonds.

U2 - 10.1021/om030235u

DO - 10.1021/om030235u

M3 - Article

AN - SCOPUS:0041841293

VL - 22

SP - 3025

EP - 3027

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 15

ER -

Synthesis and structural characterization of a novel dipalladium complex with an unprecedented PdCN bonding motif

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