Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp3 carbon chains

Gareth R. Owen; Jürgen Stahl; Frank Hampel; J. A. Gladysz

doi:10.1021/om0493558

Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp³ carbon chains

Gareth R. Owen, Jürgen Stahl, Frank Hampel, J. A. Gladysz^*

^*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

43 Dyfyniadau (Scopus)

Crynodeb

When trans,trans-(C₆F₅)(p-tol₃P) ₂Pt(C≡C)₃Pt-(P-p-tol₃)₂(C ₆F₅) and Ar₂P(CH₂) _mPAr₂ (m l Ar = 8 / p-tol, 10 / Ph, 11 / Ph, 12 / Ph, 14 / p-tol) are reacted, p-tol₃P is displaced to give products in which the diphosphines span the platinum end groups. One crystal structure (m = 14) shows a double-helical conformation in which the sp³ carbon chains twist around the sp chain, and others (m = 10, 11) show nonhelical conformations with lateral shielding of the sp chain.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	5889-5892
Nifer y tudalennau	4
Cyfnodolyn	Organometallics
Cyfrol	23
Rhif cyhoeddi	25
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1021/om0493558
Statws	Cyhoeddwyd - 6 Rhag 2004
Cyhoeddwyd yn allanol	Ie

Mynediad at Ddogfen

10.1021/om0493558Trwydded: CC BY-NC-ND

Dyfynnu hyn

@article{e1dc0e80059a41d19e4b2f37cd35670f,

title = "Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp3 carbon chains",

abstract = "When trans,trans-(C6F5)(p-tol3P) 2Pt(C≡C)3Pt-(P-p-tol3)2(C 6F5) and Ar2P(CH2) mPAr2 (m l Ar = 8 / p-tol, 10 / Ph, 11 / Ph, 12 / Ph, 14 / p-tol) are reacted, p-tol3P is displaced to give products in which the diphosphines span the platinum end groups. One crystal structure (m = 14) shows a double-helical conformation in which the sp3 carbon chains twist around the sp chain, and others (m = 10, 11) show nonhelical conformations with lateral shielding of the sp chain.",

author = "Owen, {Gareth R.} and J{\"u}rgen Stahl and Frank Hampel and Gladysz, {J. A.}",

year = "2004",

month = dec,

day = "6",

doi = "10.1021/om0493558",

language = "English",

volume = "23",

pages = "5889--5892",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "25",

}

TY - JOUR

T1 - Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp3 carbon chains

AU - Owen, Gareth R.

AU - Stahl, Jürgen

AU - Hampel, Frank

AU - Gladysz, J. A.

PY - 2004/12/6

Y1 - 2004/12/6

N2 - When trans,trans-(C6F5)(p-tol3P) 2Pt(C≡C)3Pt-(P-p-tol3)2(C 6F5) and Ar2P(CH2) mPAr2 (m l Ar = 8 / p-tol, 10 / Ph, 11 / Ph, 12 / Ph, 14 / p-tol) are reacted, p-tol3P is displaced to give products in which the diphosphines span the platinum end groups. One crystal structure (m = 14) shows a double-helical conformation in which the sp3 carbon chains twist around the sp chain, and others (m = 10, 11) show nonhelical conformations with lateral shielding of the sp chain.

AB - When trans,trans-(C6F5)(p-tol3P) 2Pt(C≡C)3Pt-(P-p-tol3)2(C 6F5) and Ar2P(CH2) mPAr2 (m l Ar = 8 / p-tol, 10 / Ph, 11 / Ph, 12 / Ph, 14 / p-tol) are reacted, p-tol3P is displaced to give products in which the diphosphines span the platinum end groups. One crystal structure (m = 14) shows a double-helical conformation in which the sp3 carbon chains twist around the sp chain, and others (m = 10, 11) show nonhelical conformations with lateral shielding of the sp chain.

U2 - 10.1021/om0493558

DO - 10.1021/om0493558

M3 - Article

AN - SCOPUS:10444280990

VL - 23

SP - 5889

EP - 5892

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 25

ER -

Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp3 carbon chains

Crynodeb

Mynediad at Ddogfen

Ôl bys

Dyfynnu hyn

Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp³ carbon chains