Solvent-free aerobic epoxidation of 1-decene using supported cobalt catalysts

Rebecca V. Engel, Raiedhah Alsaiari, Ewa Nowicka, Peter J. Miedziak, Simon A. Kondrat, David J. Morgan, Jennifer K. Edwards, Graham J. Hutchings*

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

13 Wedi eu Llwytho i Lawr (Pure)

Crynodeb

In this study, active cobalt-based catalysts are reported for the solvent-free aerobic epoxidation of 1-decene as a non-noble metal, alternative to the conventionally used gold catalyst. No sacrificial reductant is applied and air is used as primary oxidant at ambient pressure. The influence of different radical initiators and the product distribution over time is investigated. Evidence for a reaction mechanism similar to the previously reported gold-catalysed aerobic epoxidation of 1-decene, is given. Furthermore, it is shown that the catalyst stability is influenced by the choice of the support.

Iaith wreiddiolSaesneg
CyfnodolynCatalysis Today
Dyddiad ar-lein cynnar23 Medi 2018
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsE-gyhoeddi cyn argraffu - 23 Medi 2018
Cyhoeddwyd yn allanolIe

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Gweld gwybodaeth am bynciau ymchwil 'Solvent-free aerobic epoxidation of 1-decene using supported cobalt catalysts'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

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