Selective oxidation of n-butanol using gold-palladium supported nanoparticles under base-free conditions

Inaki Gandarias, Peter J. Miedziak, Ewa Nowicka, Mark Douthwaite, David J. Morgan, Graham J. Hutchings, Stuart H. Taylor*

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

11 Dyfyniadau (Scopus)

Crynodeb

The base-free selective catalytic oxidation of n-butanol by O2 in an aqueous phase has been studied using Au-Pd bimetallic nanoparticles supported on titania. Au-Pd/TiO2 catalysts were prepared by different methods: wet impregnation, physical mixing, deposition-precipitation and sol immobilisation. The sol immobilisation technique, which used polyvinyl alcohol (PVA) as the stabilizing agent, gave the catalyst with the smallest average particle size and the highest stable activity and selectivity towards butyric acid. Increasing the amount of PVA resulted in a decrease in the size of the nanoparticles. However, it also reduced activity by limiting the accessibility of reactants to the active sites. Heating the catalyst to reflux with water at 90°C for 1 h was the best method to enhance the surface exposure of the nanoparticles without affecting their size, as determined by TEM, X-ray photoelectron spectroscopy and CO chemisorption analysis. This catalyst was not only active and selective towards butyric acid but was also stable under the operating conditions.

Iaith wreiddiolSaesneg
Tudalennau (o-i)473-480
Nifer y tudalennau8
CyfnodolynChemsuschem
Cyfrol8
Rhif cyhoeddi3
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 13 Chwef 2015
Cyhoeddwyd yn allanolIe

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