Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions

Rosenildo Da Costa, Thierry Buffeteau, André Del Guerzo, Nathan D. McClenaghan, Jean-Marc Vincent

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

Crynodeb

The Ru(bipy)3 dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate–carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production
Iaith wreiddiolSaesneg
Tudalennau (o-i)8250–8252
CyfnodolynChemical Communications
Cyfrol47
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 2011

Ôl bys

Gweld gwybodaeth am bynciau ymchwil 'Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate–carboxylic acid H-bond interactions'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

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