Preparation of Biomass-Derived Furfuryl Acetals by Transacetalization Reactions Catalyzed by Nanoporous Aluminosilicates

Liam A. Bailey, Takudzwa Bere, Thomas E. Davies, Stuart H. Taylor, Andrew Graham*

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

1 Wedi eu Llwytho i Lawr (Pure)

Crynodeb

Nanoporous aluminosilicate materials efficiently catalyze the formation of furaldehyde dimethyl acetal directly from methanol in high yields and in short reaction times. The facile nature of this reaction has led to the development of a telescoped protocol in which the acyclic acetal is produced in situ and subsequently functions as a substrate for a transacetalization reaction with glycerol to produce the corresponding dioxane and dioxolane products which are potentially useful biofuel additives. These products are generated in high yield without the requirement for high reaction temperatures of prolonged reaction times, and the aluminosilicate catalysts are operationally simple to produce, are effective with either purified furaldehyde or crude furaldehyde and are fully recyclable.
Iaith wreiddiolSaesneg
Rhif yr erthygl2c03968
Tudalennau (o-i)13759-13764
Nifer y tudalennau6
CyfnodolynACS Sustainable Chemistry and Engineering
Cyfrol10
Rhif cyhoeddi41
Dyddiad ar-lein cynnar29 Medi 2022
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 17 Hyd 2022

Ôl bys

Gweld gwybodaeth am bynciau ymchwil 'Preparation of Biomass-Derived Furfuryl Acetals by Transacetalization Reactions Catalyzed by Nanoporous Aluminosilicates'. Gyda’i gilydd, maen nhw’n ffurfio ôl bys unigryw.

Dyfynnu hyn