Oxidative degradation of phenol using in situ generated hydrogen peroxide combined with fenton's process

Ricci Underhill, Richard J. Lewis, Simon J. Freakley, Mark Douthwaite, Peter J. Miedziak, Ouardia Akdim, Jennifer K. Edwards, Graham J. Hutchings*

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygl adolyguadolygiad gan gymheiriaid

15 Dyfyniadau (Scopus)

Crynodeb

Oxidative destruction of organic compounds in water streams could significantly reduce environmental effects associated with discharging waste. We report the development of a process to oxidise phenol in aqueous solutions, a model for waste stream contaminants, using Fenton's reactions combined with in situ synthesised hydrogen peroxide (H2O2). Bifunctional palladium-iron supported catalysts, where Pd is responsible for H2O2 synthesis while Fe ensures the production of reactive oxygen species required for the degradation of phenol to less toxic species is reported. A comparison is made between in situ generated and commercial H2O2 and the effect of phenol degradation products on catalyst stability is explored.

Iaith wreiddiolSaesneg
Tudalennau (o-i)417-425
Nifer y tudalennau9
CyfnodolynJohnson Matthey Technology Review
Cyfrol62
Rhif cyhoeddi4
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 1 Hyd 2018
Cyhoeddwyd yn allanolIe

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