Nanoporous aluminosilicate mediated transacetalization reactions: Application in glycerol valorization

Lydia Yip; Tomasz M. Kubczyk; Thomas E. Davies; Stuart H. Taylor; David C. Apperley; Andrew E. Graham

doi:10.1039/c2cy20188g

Nanoporous aluminosilicate mediated transacetalization reactions: Application in glycerol valorization

Lydia Yip, Tomasz M. Kubczyk, Thomas E. Davies, Stuart H. Taylor, David C. Apperley, Andrew E. Graham^*

^*Awdur cyfatebol y gwaith hwn

Cyfadran Cyfrifiadureg, Peirianneg a Gwyddoniaeth

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

6 Dyfyniadau (Scopus)

Crynodeb

Nanoporous silicate materials, produced using an evaporation-induced self-assembly (EISA) approach, are highly effective catalysts for transacetalization reactions. Both acyclic acetals and ketals undergo rapid exchange in the presence of low loadings of nanoporous aluminosilicate materials and diols and triols to generate the corresponding cyclic acetals and ketals in excellent yield. The protocol is rapid, employs mild conditions, and the catalyst can be recycled a number of times without loss of activity.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	2258-2263
Nifer y tudalennau	6
Cyfnodolyn	Catalysis Science and Technology
Cyfrol	2
Rhif cyhoeddi	11
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1039/c2cy20188g
Statws	Cyhoeddwyd - 2012

Mynediad at Ddogfen

10.1039/c2cy20188gTrwydded: CC BY-NC-ND

Dyfynnu hyn

@article{0db6c643569f417c9f08c74705210e25,

title = "Nanoporous aluminosilicate mediated transacetalization reactions: Application in glycerol valorization",

abstract = "Nanoporous silicate materials, produced using an evaporation-induced self-assembly (EISA) approach, are highly effective catalysts for transacetalization reactions. Both acyclic acetals and ketals undergo rapid exchange in the presence of low loadings of nanoporous aluminosilicate materials and diols and triols to generate the corresponding cyclic acetals and ketals in excellent yield. The protocol is rapid, employs mild conditions, and the catalyst can be recycled a number of times without loss of activity. ",

author = "Lydia Yip and Kubczyk, {Tomasz M.} and Davies, {Thomas E.} and Taylor, {Stuart H.} and Apperley, {David C.} and Graham, {Andrew E.}",

year = "2012",

doi = "10.1039/c2cy20188g",

language = "English",

volume = "2",

pages = "2258--2263",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Nanoporous aluminosilicate mediated transacetalization reactions

T2 - Application in glycerol valorization

AU - Yip, Lydia

AU - Kubczyk, Tomasz M.

AU - Davies, Thomas E.

AU - Taylor, Stuart H.

AU - Apperley, David C.

AU - Graham, Andrew E.

PY - 2012

Y1 - 2012

N2 - Nanoporous silicate materials, produced using an evaporation-induced self-assembly (EISA) approach, are highly effective catalysts for transacetalization reactions. Both acyclic acetals and ketals undergo rapid exchange in the presence of low loadings of nanoporous aluminosilicate materials and diols and triols to generate the corresponding cyclic acetals and ketals in excellent yield. The protocol is rapid, employs mild conditions, and the catalyst can be recycled a number of times without loss of activity.

AB - Nanoporous silicate materials, produced using an evaporation-induced self-assembly (EISA) approach, are highly effective catalysts for transacetalization reactions. Both acyclic acetals and ketals undergo rapid exchange in the presence of low loadings of nanoporous aluminosilicate materials and diols and triols to generate the corresponding cyclic acetals and ketals in excellent yield. The protocol is rapid, employs mild conditions, and the catalyst can be recycled a number of times without loss of activity.

U2 - 10.1039/c2cy20188g

DO - 10.1039/c2cy20188g

M3 - Article

AN - SCOPUS:84867381410

SN - 2044-4753

VL - 2

SP - 2258

EP - 2263

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 11

ER -

Nanoporous aluminosilicate mediated transacetalization reactions: Application in glycerol valorization

Crynodeb

Mynediad at Ddogfen

Ôl bys

Dyfynnu hyn