Highly efficient Meinwald rearrangement reactions of epoxides catalyzed by copper tetrafluoroborate

Mathew W. C. Robinson; Kathryn S. Pillinger; Andrew E. Graham

doi:10.1016/j.tetlet.2006.06.055

Highly efficient Meinwald rearrangement reactions of epoxides catalyzed by copper tetrafluoroborate

Mathew W. C. Robinson, Kathryn S. Pillinger, Andrew E. Graham^*

^*Awdur cyfatebol y gwaith hwn

Cyfadran Cyfrifiadureg, Peirianneg a Gwyddoniaeth

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

54 Dyfyniadau (Scopus)

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Epoxides undergo a highly efficient and selective rearrangement in the presence of catalytic quantities of copper tetrafluoroborate to give carbonyl compounds in excellent yields. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive Lewis acids frequently employed.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	5919-5921
Nifer y tudalennau	3
Cyfnodolyn	Tetrahedron Letters
Cyfrol	47
Rhif cyhoeddi	33
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1016/j.tetlet.2006.06.055
Statws	Cyhoeddwyd - 14 Awst 2006

Mynediad at Ddogfen

10.1016/j.tetlet.2006.06.055Trwydded: CC BY-NC-ND

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@article{696e2b726241412592e95ae71526452f,

title = "Highly efficient Meinwald rearrangement reactions of epoxides catalyzed by copper tetrafluoroborate",

abstract = "Epoxides undergo a highly efficient and selective rearrangement in the presence of catalytic quantities of copper tetrafluoroborate to give carbonyl compounds in excellent yields. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive Lewis acids frequently employed. ",

keywords = "Copper tetrafluoroborate, Lewis acid catalyst, Meinwald rearrangement",

author = "Robinson, {Mathew W. C.} and Pillinger, {Kathryn S.} and Graham, {Andrew E.}",

year = "2006",

month = aug,

day = "14",

doi = "10.1016/j.tetlet.2006.06.055",

language = "English",

volume = "47",

pages = "5919--5921",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "33",

}

TY - JOUR

T1 - Highly efficient Meinwald rearrangement reactions of epoxides catalyzed by copper tetrafluoroborate

AU - Robinson, Mathew W. C.

AU - Pillinger, Kathryn S.

AU - Graham, Andrew E.

PY - 2006/8/14

Y1 - 2006/8/14

N2 - Epoxides undergo a highly efficient and selective rearrangement in the presence of catalytic quantities of copper tetrafluoroborate to give carbonyl compounds in excellent yields. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive Lewis acids frequently employed.

AB - Epoxides undergo a highly efficient and selective rearrangement in the presence of catalytic quantities of copper tetrafluoroborate to give carbonyl compounds in excellent yields. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive Lewis acids frequently employed.

KW - Copper tetrafluoroborate

KW - Lewis acid catalyst

KW - Meinwald rearrangement

U2 - 10.1016/j.tetlet.2006.06.055

DO - 10.1016/j.tetlet.2006.06.055

M3 - Article

AN - SCOPUS:33745698155

VL - 47

SP - 5919

EP - 5921

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 33

ER -

Highly efficient Meinwald rearrangement reactions of epoxides catalyzed by copper tetrafluoroborate

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