Flexible scorpionates for transfer hydrogenation: The first example of their catalytic application

Nikolaos Tsoureas, Gareth R. Owen, Alex Hamilton, A. Guy Orpen

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

33 Dyfyniadau (Scopus)

Crynodeb

Rhodium and iridium complexes of flexible scorpionate ligands based on azaindole were synthesised in good yields. The complexes were characterised in solution and in the solid state. Structural characterisation revealed a B-H-metal interaction, which is retained in solution. Given the greater flexibility of the ligand and potential cooperative effect of boron, the complexes were tested for their activity in the transfer hydrogenation of ketones.

Iaith wreiddiolSaesneg
Tudalennau (o-i)6039-6044
Nifer y tudalennau6
CyfnodolynDalton Transactions
Rhif cyhoeddi43
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 6 Tach 2008
Cyhoeddwyd yn allanolIe

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