Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

Andrew Graham; Mathew W. C. Robinson; A. Matthew Davies; Richard Buckle; Ian Mabbett; Stuart H. Taylor

doi:10.1039/B900719A

Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

Andrew Graham, Mathew W. C. Robinson, A. Matthew Davies, Richard Buckle, Ian Mabbett, Stuart H. Taylor

Cyfadran Cyfrifiadureg, Peirianneg a Gwyddoniaeth

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

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Mesoporous aluminosilicates efficiently catalyze the ring-opening of epoxides to produce ß-alkoxyalcohols in high yields under extremely mild reaction conditions. These materials also catalyze the corresponding Meinwald rearrangement in non-nucleophilic solvents to give aldehydes which can be trapped in situ to provide the corresponding acetals in an efficient tandem process.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	2559 - 2564
Nifer y tudalennau	5
Cyfnodolyn	Organic and Biomolecular Chemistry
Cyfrol	7
Rhif cyhoeddi	12
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1039/B900719A
Statws	Cyhoeddwyd - 21 Ebr 2009

Mynediad at Ddogfen

10.1039/B900719ATrwydded: CC BY-NC-ND

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@article{559cdcffefdd47ec86f4dad03ffd9fe6,

title = "Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates",

abstract = "Mesoporous aluminosilicates efficiently catalyze the ring-opening of epoxides to produce {\ss}-alkoxyalcohols in high yields under extremely mild reaction conditions. These materials also catalyze the corresponding Meinwald rearrangement in non-nucleophilic solvents to give aldehydes which can be trapped in situ to provide the corresponding acetals in an efficient tandem process.",

keywords = "epoxide, ring-opening, meinwald rearrangement reactions, catalyzed, mesoporous aluminosilicates",

author = "Andrew Graham and Robinson, {Mathew W. C.} and Davies, {A. Matthew} and Richard Buckle and Ian Mabbett and Taylor, {Stuart H.}",

year = "2009",

month = apr,

day = "21",

doi = "10.1039/B900719A",

language = "English",

volume = "7",

pages = "2559 -- 2564",

journal = "Organic and Biomolecular Chemistry",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

AU - Graham, Andrew

AU - Robinson, Mathew W. C.

AU - Davies, A. Matthew

AU - Buckle, Richard

AU - Mabbett, Ian

AU - Taylor, Stuart H.

PY - 2009/4/21

Y1 - 2009/4/21

N2 - Mesoporous aluminosilicates efficiently catalyze the ring-opening of epoxides to produce ß-alkoxyalcohols in high yields under extremely mild reaction conditions. These materials also catalyze the corresponding Meinwald rearrangement in non-nucleophilic solvents to give aldehydes which can be trapped in situ to provide the corresponding acetals in an efficient tandem process.

AB - Mesoporous aluminosilicates efficiently catalyze the ring-opening of epoxides to produce ß-alkoxyalcohols in high yields under extremely mild reaction conditions. These materials also catalyze the corresponding Meinwald rearrangement in non-nucleophilic solvents to give aldehydes which can be trapped in situ to provide the corresponding acetals in an efficient tandem process.

KW - epoxide

KW - ring-opening

KW - meinwald rearrangement reactions

KW - catalyzed

KW - mesoporous aluminosilicates

U2 - 10.1039/B900719A

DO - 10.1039/B900719A

M3 - Article

VL - 7

SP - 2559

EP - 2564

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 12

ER -

Epoxide ring-opening and Meinwald rearrangement reactions of epoxides catalyzed by mesoporous aluminosilicates

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