Enhancement in the rate of nitrate degradation on Au- And Ag-decorated TiO2 photocatalysts

Thomas Caswell, Mbongiseni W. Dlamini, Peter J. Miedziak, Samuel Pattisson, Philip R. Davies, Stuart H. Taylor, Graham J. Hutchings*

*Awdur cyfatebol y gwaith hwn

    Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

    Crynodeb

    The solar-driven reduction of nitrate to nitrogen has been studied in the presence of a formate hole scavenger, over a series of Au- and Ag-decorated TiO2 catalysts. In this study, the catalyst preparation protocol was found to influence the nitrate transformation in the order: incipient wetness impregnation > stabilizer-free sol immobilization > sol immobilization. However, the sequence of performing specific treatment steps such as drying, calcination and sieving had a less pronounced effect. Low-conversion conditions were utilized to study the photo-degradation of nitrate over a range of monometallic and bimetallic catalysts with metal concentrations in the range M = 0-1 wt% (M: Au, Ag, Pd, AuAg). Our findings demonstrate that selectively degrading nitrate to N2 over these co-catalysts is non-trivial and is metal content dependent. For Au-doped TiO2 catalysts, the highest activity was measured over 0.2 wt% Au/TiO2 while a higher metal loading of 0.4 wt% was required for the Ag/TiO2 photocatalyst. Product selectivity was also demonstrated to be dependent on metal and metal loading: approximately 22% nitrite selectivity was determined over a 0.1 wt% Ag-doped catalysts, however this product was not detected when utilising Au-doped catalysts. Total selectivity to dinitrogen was shown to be possible on both Au and Ag doped catalysts, and again this was dependent on the concentration of the metal (Ag > 0.3 wt%; 0.2 < Au ≥ 0.4 wt%).

    Iaith wreiddiolSaesneg
    Tudalennau (o-i)2082-2091
    Nifer y tudalennau10
    CyfnodolynCatalysis Science and Technology
    Cyfrol10
    Rhif cyhoeddi7
    Dyddiad ar-lein cynnar3 Maw 2020
    Dynodwyr Gwrthrych Digidol (DOIs)
    StatwsCyhoeddwyd - 7 Ebr 2020

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