Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

David Antonelli; Hung V. Mai; Tuan K.A. Hoang; Ahmad Hamaed; Michel Trudeau

doi:10.1039/c001964j

Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

David Antonelli, Hung V. Mai, Tuan K.A. Hoang, Ahmad Hamaed, Michel Trudeau

Cyfadran Cyfrifiadureg, Peirianneg a Gwyddoniaeth

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

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Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	3206 - 3208
Nifer y tudalennau	2
Cyfnodolyn	Chemistry Communications
Cyfrol	46
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1039/c001964j
Statws	Cyhoeddwyd - 1 Ion 2010

Mynediad at Ddogfen

10.1039/c001964jTrwydded: CC BY-NC-ND

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@article{30900deae6d74d28ab71157fca9662be,

title = "Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage",

abstract = "Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.",

keywords = "kubas-type, hydrogen storage",

author = "David Antonelli and Mai, {Hung V.} and Hoang, {Tuan K.A.} and Ahmad Hamaed and Michel Trudeau",

year = "2010",

month = jan,

day = "1",

doi = "10.1039/c001964j",

language = "English",

volume = "46",

pages = "3206 -- 3208",

journal = "Chemistry Communications",

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TY - JOUR

T1 - Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

AU - Antonelli, David

AU - Mai, Hung V.

AU - Hoang, Tuan K.A.

AU - Hamaed, Ahmad

AU - Trudeau, Michel

PY - 2010/1/1

Y1 - 2010/1/1

N2 - Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

AB - Cyclopentadienyl chromium hydrazide gels were synthesized from the protonolysis reaction between bis(cyclopentadienyl) chromium and hydrazine. The amorphous products containing low valent chromium species are exploited as substrates for Kubas-type hydrogenstorage. These materials demonstrate enthalpies that rise from 10 to 45 kJ mol-1 and show a retention of 49% of the adsorption capacity at 298 K relative to 77 K, compared to values of 10–15% for most MOFs and amorphous carbons.

KW - kubas-type

KW - hydrogen storage

U2 - 10.1039/c001964j

DO - 10.1039/c001964j

M3 - Article

C2 - 20424775

VL - 46

SP - 3206

EP - 3208

JO - Chemistry Communications

JF - Chemistry Communications

ER -

Cyclopentadienyl chromium hydrazide gels for Kubas-type hydrogen storage

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