Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

Mathew W. C. Robinson; Kathryn S. Pillinger; Ian Mabbett; David A. Timms; Andrew E. Graham

doi:10.1016/j.tet.2010.08.078

Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

Mathew W. C. Robinson, Kathryn S. Pillinger, Ian Mabbett, David A. Timms, Andrew E. Graham

Cyfadran Cyfrifiadureg, Peirianneg a Gwyddoniaeth

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

58 Dyfyniadau (Scopus)

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Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	8377-8382
Nifer y tudalennau	6
Cyfnodolyn	Tetrahedron Letters
Cyfrol	66
Rhif cyhoeddi	43
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1016/j.tet.2010.08.078
Statws	Cyhoeddwyd - 23 Hyd 2010

Mynediad at Ddogfen

10.1016/j.tet.2010.08.078Trwydded: CC BY-NC-ND

Dyfynnu hyn

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title = "Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides",

abstract = "Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed. ",

keywords = "Copper(II) tetrafluoroborate, Lewis acid catalyst, Meinwald rearrangement, Nanoporous aluminosilicates",

author = "Robinson, {Mathew W. C.} and Pillinger, {Kathryn S.} and Ian Mabbett and Timms, {David A.} and Graham, {Andrew E.}",

year = "2010",

month = oct,

day = "23",

doi = "10.1016/j.tet.2010.08.078",

language = "English",

volume = "66",

pages = "8377--8382",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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T1 - Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

AU - Robinson, Mathew W. C.

AU - Pillinger, Kathryn S.

AU - Mabbett, Ian

AU - Timms, David A.

AU - Graham, Andrew E.

PY - 2010/10/23

Y1 - 2010/10/23

N2 - Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

AB - Epoxides undergo a highly efficient Meinwald rearrangement in the presence of catalytic quantities of copper(II) tetrafluoroborate to give carbonyl compounds in high yields and with excellent selectivity. The low toxicity and ease of handling of this reagent make it an attractive alternative to the more corrosive or costly Lewis acids frequently employed.

KW - Copper(II) tetrafluoroborate

KW - Lewis acid catalyst

KW - Meinwald rearrangement

KW - Nanoporous aluminosilicates

U2 - 10.1016/j.tet.2010.08.078

DO - 10.1016/j.tet.2010.08.078

M3 - Article

AN - SCOPUS:77957337153

VL - 66

SP - 8377

EP - 8382

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 43

ER -

Copper(II) tetrafluroborate-promoted Meinwald rearrangement reactions of epoxides

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