Barium manganate in microwave-assisted oxidation reactions: synthesis of lactones by oxidative cyclization of diols

Mark C. Bagley*, Zhifan Lin, David J. Phillips, Andrew E. Graham

*Awdur cyfatebol y gwaith hwn

Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

22 Dyfyniadau (Scopus)

Crynodeb

Microwave irradiation of a range of diols at 150 °C in acetonitrile in the presence of three equivalents of barium manganate facilitates a novel tandem oxidation/heterocyclocondensation to give the corresponding lactone, including both small and medium ring lactones, in only one hour and in high yield without the need for chromatographic purification.

Iaith wreiddiolSaesneg
Tudalennau (o-i)6823-6825
Nifer y tudalennau3
CyfnodolynTetrahedron Letters
Cyfrol50
Rhif cyhoeddi49
Dynodwyr Gwrthrych Digidol (DOIs)
StatwsCyhoeddwyd - 9 Rhag 2009

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