A new hybrid scorpionate ligand: A study of the metal-boron bond within metallaboratrane complexes

Gareth R. Owen, P. Hugh Gould, Jonathan P.H. Charmant, Alex Hamilton, Saowanit Saithong

    Allbwn ymchwil: Cyfraniad at gyfnodolynErthygladolygiad gan gymheiriaid

    33 Dyfyniadau (Scopus)

    Crynodeb

    A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)2(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)3] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh 3){κ4-SSBS-B(mt)3}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.

    Iaith wreiddiolSaesneg
    Tudalennau (o-i)392-400
    Nifer y tudalennau9
    CyfnodolynDalton Transactions
    Cyfrol39
    Rhif cyhoeddi2
    Dynodwyr Gwrthrych Digidol (DOIs)
    StatwsCyhoeddwyd - 26 Chwef 2010

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