A new hybrid scorpionate ligand:  A study of the metal-boron bond within metallaboratrane complexes

Gareth R. Owen; P. Hugh Gould; Jonathan P.H. Charmant; Alex Hamilton; Saowanit Saithong

doi:10.1039/b911651f

A new hybrid scorpionate ligand: A study of the metal-boron bond within metallaboratrane complexes

Gareth R. Owen, P. Hugh Gould, Jonathan P.H. Charmant, Alex Hamilton, Saowanit Saithong

Allbwn ymchwil: Cyfraniad at gyfnodolyn › Erthygl › adolygiad gan gymheiriaid

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A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)₂(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)₃] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh ₃){κ⁴-SSBS-B(mt)₃}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.

Iaith wreiddiol	Saesneg
Tudalennau (o-i)	392-400
Nifer y tudalennau	9
Cyfnodolyn	Dalton Transactions
Cyfrol	39
Rhif cyhoeddi	2
Dynodwyr Gwrthrych Digidol (DOIs)	https://doi.org/10.1039/b911651f
Statws	Cyhoeddwyd - 26 Chwef 2010

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10.1039/b911651f

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@article{c73d02d6ed5548a099463ee9e4cc54a3,

title = "A new hybrid scorpionate ligand: A study of the metal-boron bond within metallaboratrane complexes",

abstract = "A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)2(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)3] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh 3){κ4-SSBS-B(mt)3}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.",

author = "Owen, {Gareth R.} and {Hugh Gould}, P. and Charmant, {Jonathan P.H.} and Alex Hamilton and Saowanit Saithong",

year = "2010",

month = feb,

day = "26",

doi = "10.1039/b911651f",

language = "English",

volume = "39",

pages = "392--400",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "2",

}

TY - JOUR

T1 - A new hybrid scorpionate ligand

T2 - A study of the metal-boron bond within metallaboratrane complexes

AU - Owen, Gareth R.

AU - Hugh Gould, P.

AU - Charmant, Jonathan P.H.

AU - Hamilton, Alex

AU - Saithong, Saowanit

PY - 2010/2/26

Y1 - 2010/2/26

N2 - A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)2(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)3] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh 3){κ4-SSBS-B(mt)3}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.

AB - A new boron-based hybrid scorpionate ligand based upon one 2-mercaptopyridine (mp) and two 1-methyl-imidazoyl-2-thione (mt) units, Na[HB(mt)2(mp)] has been prepared. This new ligand together with the recently reported ligand K[HB(mp)3] have been used to prepare analogues of the original metallaboratrane complex [Ru(CO)(PPh 3){κ4-SSBS-B(mt)3}]. The effect of tautomerisation of the ligand arms upon the electronic properties of the boron and metal centres is examined in an attempt to probe further the nature of the metal-boron bond within metallaboratrane complexes.

U2 - 10.1039/b911651f

DO - 10.1039/b911651f

M3 - Article

AN - SCOPUS:77149173435

VL - 39

SP - 392

EP - 400

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 2

ER -

A new hybrid scorpionate ligand: A study of the metal-boron bond within metallaboratrane complexes

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